It was narrated that 'Abdullah bin Arqam said:
"The Messenger of Allah said: 'If anyone of you needs to defecate and the immediate call to prayer (Iqamah) is given, let him start with (relieving himself).'" (ES)
English reference (ES): Vol. 1, Book 1, Hadith 616 (ES)
Arabic reference (ES): Book 1, Hadith 659 (ES)